Process for producing a high tension steel sheet product having an excellent low-temperature toughness with a yield point of 40 kg/mm2 or higher

ABSTRACT

The production process characterized in that a steel ingot or slab containing not less than 0.004% of TiN not larger than 0.02μ is heated to a temperature not higher than 1150° C. and rolled, and growth of the γ grains during this heating and rolling step is prevented by TiN to improve the toughness, and the resultant steel product has an excellent low-temperature toughness with a yield point of 40 kg/mm 2  or higher, and is useful as hot rolled or as heated at a temperature ranging from 300° to 750° C. after the hot rolling.

This is a continuation of Ser. No. 029,868, filed Apr. 13, 1979,abandoned, reissue application of U.S. Pat. No. 4,105,474, which maturedfrom Ser. No. 786,946, filed Apr. 12, 1977. .Iaddend.

BACKGROUND OF THE INVENTION

1. Field of the Invention:

The present invention relates to a process for producing high tensionsteel products, such as plates, sheets and strips (herein calledsheets), having an excellent low-temperature toughness with a yieldpoint of 40 kg/mm² or higher.

The steel products according to the present invention are useful as hotrolled or as heated at a temperature ranging from 300° to 750° C. afterthe hot rolling.

2. Description of Prior Art:

Conventionally, steel sheets such as for pipe lines in cold climateregions whih are required to have high strength and toughness in the "asrolled" condition have been produced by a method called "controlledrolling" (hereinafter abridged as CR), and mainly Nb-containing steelshave been used for this purpose.

Generally, the CR method is composed of two steps; the first step is aheating step and the second step is a rolling step (cooling), if largelyclassified. The following considerations must be made in these steps,respectively.

(1) In the heating step, it is required to dissolve elements such as Nband V enough for refinement of the structure and precipitationhardening, and it is required to maintain the austenite grains duringthe heating (heated γ grains) as fine as possible.

(2) In the rolling step, it is necessary to recrystallize the heated γgrains repeatedly by rolling to obtain refined rolled austenite grains(rolled γ grains), and it is necessary to elongate the rolled γ grainsand reduce their thickness by rolling in their non-recrystallizationzone so as to obtain refinement of the rolled structure.

However, in case of Nb-containing steels as commonly used, Nb(CN) isstable at high temperatures and it is difficult to ressolve Nb(CN)consistently and satisfactorily even by a long heating time if theheating temperature is not higher than 1150° C.

If the heating temperature is raised, it is possible to attain asatisfactory solid solution of Nb(CN). On the other hand, the heated γgrains grow excessively, thus resulting in considerable deterioration ofthe toughness of the rolled steel.

Therefore, in the CR method, it is necessary to lower the heatingtemperature to keep the heated γ grains smaller when severelow-temperature toughness is required. On the other hand, when theheating temperature is lowered, the amount of Nb in solid solutionincreases or decreases depending on a slight change in the heatingtemperature and time in case of the commonly used Nb-containing steels.Even under the same rolling conditions, the resultant strengthfluctuates in a wide range depending on the change in the amount of thesolid solution Nb, and high strength, if obtained, is accompanied withdeterioration of toughness. Thus, it is difficult to obtain a stablebalance between strength and toughness.

The above difficulties can be attributed to the fact that toughnesslowers in proportion to the increase of strength, and the increase ofstrength corresponds to the increase of the amount of Nb(CN) in solidsolution and the coarsening of the heated γ grains, so that the steelstructure will be made of coarse and mixed grains.

However, in the conventional CR method, proper consideration has notbeen given to the fact that the heated γ grains coarsen when enoughNb(CN) is dissolved in solid solution during the heating step, and thustoughness is deteriorated.

As described above, it is necessary to prevent the growth of the heatedγ grains by means of the precipitation in order to maintain fine heatedγ grains and improve toughness.

For this purpose, it is required to lower the heating temperature andkeep the precipitates such as Nb(CN) from solid solution during theheating. On the other hand, in order to maintain the strength, it isnecessary to dissolve Nb(CN) into solid solution as much aspossibleduring the heating so as to precipitate it during the coolingafter the rolling to strengthen the steel. For this purpose, it isdesirable to maintain the heating temperature as high as possible.

SUMMARY OF THE INVENTION

Therefore, one of the objects of the present invention is to solve thecompletely contradictory problems as mentioned above, and provide asteel sheet having remarkably smaller heated γ grains than those ofconventional steels in spite of Nb(CN) in solid solution for strength,and showing a stable and excellent balance between strength andtoughness if appropriate rolling conditions are applied thereto.

The features of the present invention may be summarized as follows:

(1) In order to attain satisfactory and stable Nb(CN) in solid solution,the carbon content is lowered to an extreme degree as understood fromthe solubility product relation.

(2) The growth of the heated γ grains due to full solid solution ofNb(CN) is prevented by TiN which is stronger than Nb(CN) for preventionof the growth of the heated γ grains, and

(3) Optimum rolling conditions are selected.

By the above features in combination, it is possible to utilize Nb(CN)and TiN separately for different purposes; the former for strengtheningthe steel and the latter for preventing the growth of the heated γgrains, and thus the problem in the heating step can be solved.

Starting from the fine heated γ grains, a rolled structure having stillfiner grains can be obtained by rolling under proper conditions.Remarkable strength and toughness can be obtained through the decreasein the pearlite proportion attained by the lowered carbon content aswell through the grain refinement.

Regarding improvement of the steel toughness by refinement of the heatedγ grains, the present inventors disclosed a method therefor in JapanesePatent Application Sho 49-103088, and the present inventors haveconducted further various extensive studies on production of a hightension steel having excellent toughness at low temperatures, and havefound that the toughness can be stabilized and improved remarkablyaccording to the production process of the present invention.

The production process according to the present invention ischaracterized in that a steel ingot or slab containing not less than0.004% of TiN not larger than 0.02μ is heated to a temperature of orbelow 1150° C. and rolled, and growth of the γ grains during thisheating and rolling step is prevented by TiN to improve the toughness.

DETAILED DESCRIPTION OF THE INVENTION

The present invention will be described in detail referring to theattached drawings.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 shows the relation between the heated γ grain size and thecontent of TiN (%) not larger than 0.02μ, when heated to 1150° C. andheld at that temperature for 60 minutes.

FIG. 2 shows the relation between the heating temperatures and theheated γ grain size when the steel No. 2 in Table 1 according to thepresent invention is heated to various temperatures and held at suchtemperatures for 60 minutes.

FIG. 3 shows the relation between the ratio of NaS TiN/N (marked by O)and the heating temperature when the steel No. 1 in Table 1 according tothe present invention is heated to various temperatures and held at thevarious temperatures for 120 minutes and rapidly cooled in water, andthe relation between the content (%) of TiN (marked by Δ) not largerthan 0.02μ when the same steel is heated to 1150° C. and held at thattemperature for 120 minutes.

FIG. 4 shows the relation between the average cooling rate and thecontent (%) of TiN not larger than 0.02μ when the steel No. 1 in Table 1according to the present invention is cast at various solidificationrates.

FIG. 5 shows the relation between the amount of solid solution Nb andthe carbon content when steels with different carbon contents are heatedto various temperatures and held at those temperatures for 30 minutes.

FIG. 6 shows the relation between the heating temperature and theproduct of (solid solution Nb%)×(solid solution C%) when the steelaccording to the present invention is heated to various temperatures andheld at those temperatures for 60 minutes.

FIG. 7 shows the relation between the reduction amount at temperaturesnot higher than 930° C. and the yield strength YS as well as vTrs in thesteel No. 2 in Table 1 according to the present invention.

FIG. 8 shows the relation between the finishing temperature and YS aswell as vTrs in the steel No. 2 in Table 1 according to the presentinvention.

Regarding the definition of TiN not larger than 0.02μ, it also includesTi and N which are present in solid solution in the steel and TiN whichis present in the form of a precipitate and has a size not larger than0.02μ. Ti and N are present in solid solution in the steel precipitateas TiN not larger than 0.02μ during the subsequent heating andeffectively prevent the coarsening of the heated γ grains. In this case,according to the studies made by the present inventors, there is acorrelation between the heated γ grain size and the heating rate. Whenthe heating rate starting from 800° C. to a predetermined temperature isexcessively high, Ti and N do not precipitate fully, thus failing toobtain a satisfactory refinement of the heated γ grains. Therefore, inorder to refine the heated γ grains, it is necessary to decrease theheating rate to some degree, and it is preferable to control the heatingrate starting from 800° C. to a predetermined temperature to a rate notlarger than 6° C./min.

In FIG. 1 which shows the amount of TiN not larger than 0.02μ and theheated γ grain size, when the steel is heated to 1150° C. and held atthat temperature for 60 minutes, it is clear that unless TiN not largerthan 0.02μ is present in an amount of 0.004% or more, no satisfactoryrefinement of the heated γ grains can be expected. Therefore, it isnecessary that TiN not larger than 0.02μ is present in an amount notless than 0.004% in the steel before the heating. However, even whenthis condition is satisfied, the prevention effect on the coarsening ofthe heated γ grains by TiN becomes unstable if the heating temperatureis excessively high.

As is understood from FIG. 2 showing the relation between the heatingtemperature and the heated γ grain size, it is necessary to maintain theheating temperature at 1150° C. or lower, preferably in a range from900° to 1150° C. in order to obtain fine heated γ grains (not lower thanNo. 3 of ASTM).

As described above, satisfactory refinement of the heated γ grains canbe obtained under appropriate condition when TiN not larger than 0.02μis present in an amount not less than 0.004%.

Hereinbelow, descriptions will be made on the method of introducing intothe steel not less than 0.004% of TiN not larger than 0.02μ inconnection with the ingot-making method and the continuous castingmethod, respectively.

In the ingot-making method, the coarse TiN which has precipitated duringthe solidification step of the molten metal are dissolved in solidsolution in an amount not less than 0.004% during the ingot heating(soaking) step, and part of the solid solution TiN is precipitatedduring the break down rolling step and the cooling step to maintain notless than 0.004% of TiN, not larger than 0.02μ in the steel slab beforethe heating. In this case, if the Ti content is excessive, it isdifficult to maintain not less than 0.004% of TiN in solid solutionduring the ordinary ingot heating step, because TiN precipitates in anexcessively coarse form during the solidification step. Even in thiscase, the solid dissolution of TiN depends on the heating temperatureand the holding time, but if the heating temperature is too high, thereis caused the burning phenomenon and thus there is a certain maximumheating temperature inherent to the steel. Therefore, on the basis ofthe present steel making techniques, it is necessary that the content ofTi is maintained not larger than 0.03% and the amount of Ti required forthe minimum amount of 0.004% for TiN not larger than 0.02μ is 0.004% incommercial production taking into consideration the amount of Ticonsumed for formation of oxides etc. Therefore, the content of Tishould be in a range from 0.004 to 0.03%.

Next, detailed explanations will be made hereinbelow on the limitationsof the heating temperature for a solid dissolution of TiN which hasprecipitated during the solidification of the molten steel as well asthe limitations of the N and TiN contents.

For economical and stable solid dissolution of TiN during the heatingstep on a commercial level, it is effective to limit not only the Ticontent, but also the N content. The reason for setting the lower limitof the total N content at 0.001%, is that it is the minimum amountrequired for the lower limit of 0.004% of TiN which must be dissolved insolid solution during the heating step. Further, in order to maintainenough of the TiN which is dissolved in solid solution during theheating step, it is not favourable that the upper limit of the total Ncontent exceeds the upper limit of the Ti content. Therefore the upperlimit of the total N content is set at 0.009% which corresponds to 0.03%of Ti. On the other hand, if the TiN content exceeds 0.04%, thetoughness of the steel sheet is deteriorated. Thus, it is necessary toset the upper limit of the TiN content at 0.04%, but so far as the Tiand total N contents are within the ranges defined above, the TiNcontent does not exceeds 0.04%.

When the Ti and N contents are within the ranges defined in the presentinvention, the lower limit of the heating temperature for dissolving notless than 0.004% of TiN into solid solution may be 1250° C. as shown inFIG. 3 and confirmed by experiments, while the upper limit is set at1400° C. as a practically feasible temperature in spite of a partialburning of the iron oxide on the steel surface.

In the continuous casting method, where the steel slabs are madedirectly from the molten steel, if the Ti and N contents are excessive,coarse TiN precipitates during the solidification so that it isimpossible to maintain not less than 0.004% of TiN not larger than0.02μ. Therefore, just as in the ingot-making method, it is necessary tolimit the Ti and N contents respectively to 0.004 to 0.03% Ti and 0.001to 0.009% N. Even when the Ti and N contents are within these ranges, itis impossible to obtain not less than 0.004% of TiN not larger than0.02μ, if the solidification cooling rate is too slow. Therefore, it isdesirable that the cooling rate at the center portion of the steel slabis not less than 8° C./min. in average from the molten steel temperatureat the time of casting to 1100° C. When the cooling rate is below 8°C./min., it is difficult to attain not less than 0.004% of TiN notlarger than 0.02μ in the steel slab as shown in FIG. 4 and no effectiveprevention of the coarsening of the heated γ grains can be assured.

The basic features of the present invention have been describedhereinabove.

It has been further found by the present inventors that the hot rolledsteel material obtained by the above production process is reheated to atemperature ranging from 300° to 750° C., part of the fine carbides orthe solid solution carbon coagulates into carbides of favourable size sothat the toughness is improved due to the relief of stress by theprecipitation hardening of the matrix, and the arrest property asrepresented by B.DWTT (Battelle Drop Weight Tear Test), as well as theyield strength are still remarkably improved.

Explanations will be made on the limitation on the steel compositionsdefined in the present invention.

The base steel composition applicable to the present invention comprises0.01 to 0.13% C, 0.1 to 1.0% Si, 0.7 to 2.0% Mn, not more than 0.10%total Al, 0.004 to 0.03% Ti, 0.001 to 0.009% total N, 0.01 to 0.10% Nb,one or more of 0.01 to 0.15% V an 0.05 to 0.4% Mo and satisfying thecondition of

    (NB%)×(C%)≦5×10.sup.-3

Now the lower limit of 0.01% for the carbon content is set because it isa minimum amount for assuring the grain refinement of the steel materialand strength of the weld joints as well as full development of effectsof carbide forming elements such as Nb and V. On the other hand, whenthe carbon content is excessive, the amount of Nb in solid solutionreadily increases or decreases depending on even slight changes in theheating conditions as mentioned hereinbefore, and thus thestrength-toughness balance becomes unstable. Therefore, it is effectiveto define an upper limit for the carbon content for assuring a stablesolid solution of Nb(CN) in the steel slab to maintain desired strengthand toughness even in cases where the heating temperature is below 1150°C.

In FIG. 5 showing the relation between the amount of the solid solutionNb and the heating temperature in connection with various carboncontents, it is clearly shown that when the carbon content is lowered,the amount of the solid solution Nb (at a constant total Nb content of0.05%) increases, and when the carbon content is not higher than 0.13%,Nb is completely dissolved in solid solution at 1150° C.

The reason for defining the total Nb content of 0.05% is that thisamount is enough for obtaining desired strength and toughness in case of0.13% C. Thus the upper limit of the carbon content is set at 0.13%. Incases where the Nb content is large or the heating temperature is below1150° C., it is necessary to further lower the carbon content in orderto assure a stable and high enough Nb(CN) content in solid solution. Butfor this purpose it is favourable to limit not only the carbon contentby itself, but also the carbon content in relation with the Nb content.

FIG. 6 shows the experimental results concerning the relation betweenthe heating temperature and (solid solution Nb%)×(solid solution C%),and it is shown that Nb(CN) can be stably dissolved in solid solutionwhen (C%)×(Nb%)≦(solid solution Nb%)×(solid solution C%).

Within the preferable heating temperature range from 1050° to 1150° C.according to the present invention, it is preferable to define as belowdespite some fluctuation in the data.

    (C%)×(Nb%)≦5.0×10.sup.-3

For the reasons set forth above, the upper limit of the carbon contentis set at 0.13% and the carbon content is further limited in relationwith the Nb content as

    (C%)×(Nb%)≦5×10.sup.-3

Silicon is an element which comes into the steel unavoidably during thedeoxidation step, but less than 0.1% silicon causes deterioration of thetoughness. Therefore, the lower limit of the silicon content is set at0.1%. On the other hand, when the silicon content is excessive itdamages the cleanness of the steel. Thus, the upper limit of the siliconcontent is set at 1.0%.

Manganese is an important element for assuring the desired strength andtoughness of the low-carbon steel applicable to the present invention,and with manganese contents less than 0.7% the strength and toughnessare low. Thus the lower limit of the manganese content is set at 0.7%.On the other hand, when the manganese content is excessive, thetoughness of HAZ (heat affected zone) deteriorates. Thus the upper limitis set at 2.0%.

Aluminum is contained in a killed steel unavoidably from the deoxidationstep. However, when the total Al content exceeds 0.1%, not only thetoughness of HAZ but also the toughness of the weld metal are remarkablydeteriorated. Thus, the upper limit of the total Al content is set at0.1%.

Regarding the Ti and total N contents, they are limited to 0.004 to0.03% Ti and 0.001 to 0.009% total N respectively as mentionedhereinbefore. So far as Ti and N are within these ranges the TiN contentdoes not exceed 0.04%.

Niobium is added for improving the toughness of the steel material andexpanding the feasible range of the plate thickness as well as forassuring the joint strength of the welded portion. The lower limit ofthe Nb content is set at 0.01% for the reason that with Nb contents lessthan 0.01%, the desired refinement of the structure and theprecipitation strengthening by Nb cannot be attained. Thus, it isdifficult to obtain the desired strength and toughness. However, Nbaddition beyond 0.10% causes difficulty in attaining enough stable solidsolution Nb with a heating temperature not higher than 1150° C., andcauses HAZ toughness deterioration.

Vanadium, similar to niobium, may be contained up to 0.15%.

Molybdenum, similar to niobium and vanadium, increases hardening of HAZand lowers HAZ toughness and cracking resistance, if present in anexcessive amount. Therefore, the upper limit of the molybdenum is set at0.40%. The lower limits of V and Mo are set at 0.01% and 0.05%respectively, because these are minimum amounts for development of thefull effectiveness of these elements.

The steel applicable to the present invention contains phosphorus andsulfur as impurities. Regarding the phosphorus content, it is usuallynot more than 0.03% and phosphorus is not intentionally added, and alower phosphorus assures improvement of toughness. Regarding the sulfurcontent, it is usually not more than 0.02%, and it is possible to lowerthe sulfur content to about 0.0005% by the present level of thetechnics, and thereby the toughness of the steel sheet is improved. Inthe present invention, sulfur is not added intentionally.

According to one modification of the present invention, one or more of0.001 to 0.03% REM (mainly Ce, La, Pr) and 0.0005 to 0.03%, preferably0.0005 to 0.003% Ca is added under the condition of

    REM/S=1.0 to 6.0

With this modification, the toughness of the steel product obtained bythe present invention is still further improved as shown in Table 2.

REM contents less than 0.001% produce no practical improvement oftoughness, while REM contents exceeding 0.03% cause increase not only insize but also in amount of REM-oxysulfides, so that large inclusions areformed, which remarkably damage the toughness as well as the cleannessof the steel product.

Therefore, the REM content is limited to the range from 0.001 to 0.03%.Meanwhile REM is effective to improve and stabilize the toughness of thesteel sheet in correlation with the sulfur content, and the optimumrange for this purpose is 1.0 to 6.0 of REM/S. Calcium has similareffects as REM and is limited to the range from 0.0005 to 0.03%,preferably 0.0005 to 0.003%.

According to another modification of the present invention, one or moreof not more than 0.6% Cr, not more than 1.0% Cu and not more than 4.0%Ni is added under the condition of (Cu+Ni)/5+Cr+Mo≦0.90%.

The main object of addition of these elements is to improve the strengthand toughness of the steel product and to expand the feasible platethickness range. Naturally, the amounts of addition of these elementsare limited, but in the low-carbon steel applicable to the presentinvention, their upper limits may be higher than those in an ordinarycarbon steel.

Regarding chromium, an excessive chromium content increases thehardenability of HAZ and lowers the toughness and cracking resistance.Therefore, the upper limit of the chromium content is 0.6%.

Nickel is effective to improve the strength and toughness of the steelproduct without adverse effect on the hardenability and toughness ofHAZ, but nickel contents exceeding 4.0% are not favourable on thehardenability and toughness of HAZ even in case of a low-carbon steel asused in the present invention. Therefore, the upper limit of the nickelcontent is set at 4.0%.

Copper has almost similar effects as nickel and further improves thehydrogen-induced cracking resistance, but copper contents beyond 1.0%cause the copper-cracking during the rolling. Therefore, the upper limitof the copper content is set at 1.0%.

Further, the above addition elements are not added independently withintheir respective ranges, but they are are added under the condition of

    (Cu+Ni)/5+Cr+Mo≦0.90%

Otherwise the hardness of HAZ is remarkably higher so that HAZ issusceptible to cracking during a small heat-input welding, and thus thesteel cannot be used for welding.

In a still further modification of the present invention where the steelproduct after hot rolling is reheated in a temperature range from 300°to 750° C., the basic steel composition should be limited.

First of all, when the carbon content is more than 0.10%, the amount ofNb, V or Mo which is dissolved in solid solution during the slab heatingdecreases so that the amount of the fine carbide precipitates of Nb, Vor Mo during the reheating which is favourable for the strength,particularly the tensile strength, decreases.

Further, in the reheating step after the hot rolling, the fine carbidesare coagulated into a suitable size so as to improve the toughness. Forthis purpose, carbon contents less than 0.08% are remarkably effectivewithout formation of excessively large coagulated carbides.

Regarding the aluminum content, deoxidation of the molten steel byaluminum is particularly ncessary for assuring enough precipitates offine carbides of Nb, V or Mo during the reheating, which are requiredfor the desired strength. Therefore, aluminum is present in an amount of0.005% at least.

The sulfur content should be limited to 0.010% or lower so as to fullydevelop the toughness improvement by the reheating.

Descriptions have been made on the limitations of the various elementsof the steel composition used in the present invention. It has beenfurther found that it is difficult to produce a steel sheet having anexcellent low-temperature toughness and high strength of not lower than40 kg/mm² yield point by rolling the steel of the defined compositionwithin the defined range merely in an ordinary way. Therefore, in thepresent invention, the final rolling conditions are limited.

As the basic feature of the present invention, the rolling condition hasbeen defined as below.

The total reduction amount in the temperature range not higher than 930°C. is not less than 50% and the finishing temperature is not higher than830° C. Under this rolling condition, the strength and toughness of thesteel product are improved remarkably.

Explanations will be made on the limitations of the rolling condition.

When the total reduction amount at 930° C. or lower is not less than50%, the yield point and toughness are remarkably improved as shown inFIG. 7, but if the total reduction amount in the temperature range isless than 50%, it is impossible to obtain a yield point not lower than40 kg/mm² and an excellent toughness. However, even when the totalreduction amount in the temperature range is not less than 50%, thedesired strength and toughness cannot be obtained if the finishingtemperature is higher than 830° C. as shown in FIG. 8.

Regarding the finishing temperature or the rolling temperature inseveral reductions prior to the finishing, satisfactory low-temperaturetoughness is obtained even when the temperature is partially below theAr₃ transformation point if the steel composition being treated iswithin the range defined in the present invention and the rolling isdone as defined. Therefore, some dual phase (γ-α) rolling is within thescope of the present invention. However, it is desirable that thetemperature is not lower than 650° C. from the aspect of toughness.

In case where a continuous casting slab is used, the slab is introduceddirectly to the hot rolling step, for example into a heating furnace fora thick plate mill, and rolled under the condition that the totalreduction amount in the temperature range not higher than 930° C. is notless than 50% and the finishing rolling temperature is not higher than830° C.

Meanwhile, in cases where steel ingots made by the ingot-making processare used, the steel ingot is charged in a heating furnace in thebreak-down rolling step where it is heated to a temperature ranging from1250° to 1400° C. to obtain not less than 0.004% TiN in solid solution,and broken down, then subjected to the reprecipitation heating nothigher than 1150° C. in a heating furnace of the subsequent hot rollingstep, and rolled under the condition that the total reduction amount at930° C. or lower is not less than 50% and the finishing rollingtemperature is not higher than 830° C.

Regarding the cooling rate after the break-down rolling, a higher rateis better, and the effect of the cooling is more remarkable with a lowertitanium content. For the subsequent hot rolling step, a plate rollingmill is desirable, but the present invention is not limited thereto andapplicable to production of a hot steel strip and steel wire.

The basic rolling condition in the present invention has been describedabove, but this basic rolling condition should be further limited asbelow when the reheating is added according to the modification of thepresent invention. First, the total reduction amount should be limitedas below. Thus, the total reduction amount at 900° C. or lower should be60% or more. If this amount is than 60%, the amount of the fineprecipitates of Nb, V or Mo which are required for remarkably increasingthe strength and the toughness after the reheating is too low. Thus, theresultant strength and toughness are not satisfactory. On the otherhand, if the total reduction amount at 900° C. or lower is more than95%, Nb, V or Mo precipitates are coarse so that it is difficult toobtain the desired fine carbides. Thus, it is difficult to maintain thedesired strength, particularly the desired strength after the reheating.

Regarding the finishing rolling temperature, it should be furtherlimited to 800° C. or lower. Otherwise the amount of the fineprecipitates is not enough and the resultant strength and toughness arenot satisfactory. On the other hand, when the finishing temperature isbelow 500° C., it causes deterioration of toughness due to intermittentworkings and excessive precipitation of the fine carbides of Nb, V or Mowhich coagulate into coarse form during the reheating step so thatsatisfactory strength cannot be maintained.

When the finishing temperature is low, the rolling is done in aferrite-predominant zone so that the precipitates of fine carbides ofNb, V or Mo are excessively formed in the worked ferrite matrix. This israther unfavourable for the strength-toughness balance. Therefore thefinishing rolling temperature should be preferably not lower than 700°C. On the other hand, when particularly excellent toughness is to beobtained, coarse precipitates of carbides of Nb, V or Mo are promoted byexcessive working in the austenite zone of higher temperatures, and thecoarse precipitates coagulate excessively in the reheating step andproduce adverse effects on the toughness. Thus, in this case, it ispreferable to maintain the finishing temperature not higher than 780° C.Therefore, in respect of both the strength and the toughness, the mostpreferable finishing temperature range is from 700° to 780° C.

Regarding the heating step after the hot rolling step, this step isrequired for uniformly and appropriately coarsening the fine carbides ofNb, V and Mo, thus relieving the stress of the matrix due to theprecipitation hardening and improving the toughness. For this purpose, aminimum temperature of 300° C. is enough. On the other hand, when thereheating temperature is higher than 750° C., the above fine carbidesbecome coarse excessively, thus lowering the strength considerably. Themost preferable reheating temperature range for both the strength andthe toughness if from 500° to 700° C. Meanwhile, regarding the holdingtime in the reheating step, it should be at least one minute foruniformly and appropriately coarsening the fine carbides, thus relievingthe stress of the matrix due to the precipitation hardening andimproving the toughness.

On the other hand, if the holding time is longer than 10 hours, the finecarbides become excessively coarse, thus lowering the strengthconsiderably. The most preferable holding time range is from 10 minutesto 2 hours for both the strength and the toughness.

The reheating step as defined above may be done before the hot rolledsteel sheet cools down near the ordinary temperature. In this case, thereheating also has the effect of hydrogen removal.

The limitations of the production conditions in case where the reheatingstep is added have been explained before. The steel products obtained bythis modification have been found to have also an excellent resistanceagainst the hydrogen-induced cracking.

Although it has not been fully clarified, the hydrogen-induced crackingresistance may be attributed to the fact that the carbon content is lowwith less segregation, that formation of coarse carbides is prevented bythe formation of fine carbides of Nb, V or Mo, and that the stress ofthe matrix is relieved by the uniform coarsening of the fine carbidesduring the reheating step.

The present invention will be more clearly understood from the examplesshown in the tables.

Tables 1 to 3 show examples according to the basic process of thepresent invention.

Table 4 shows examples according to the modification of the presentinvention. In these examples, various steel compositions as shown (G:electric furnace steel; C1, C2, C3: refined in converter and withspecial phosphorus treatment) were made into slabs (L, M: continuouscasting) and hot rolled. The conditions of slab making and hot rollingare shown in Table 4.

Thickness of the products and tensile strength (API test piece) in thedirection at right angle to the rolling, 2 mmV Charpy impact property,B. DWTT 85% SATT property, and 2 mmV Charpy impact values of 50% bondportion of sub-merged arc welding joints welded with 30 KJ/cm input areshown in Table 4.

Table 4 further shows the number of cross sectional crackings (per 5 mmthickness) of the test pieces (ground 1 mm on both sides) afterimmersion in 100% H₂ S saturated aqueous solution (25° C.) for 96 hours.

As clearly shown in Table 4 the steels A1, B1, C1, M and N according tothe present invention show excellent tensile strength property andtoughness, particularly B.DWTT property, as well as excellent weldtoughness and hydrogen-induced cracking resistance.

The steels, A2, A3, B2, B3, C2 and C3 having the steel compositionwithin the range defined in the present invention but outside the scopeof the present invention in respect to rolling and the reheatingconditions show inferior properties.

As clearly understood from the examples, the steel product according tothe present invention has excellent strength and toughness andadditionally excellent weldability and hydrogen-induced crackingresistance.

The steel product according to the present invention is most suitablefor production of steel pipes and also is useful for fittings, tankstructural components, shipbuilding materials, frame members of variousmachine and apparatus for cold regions, etc. where the arrest propertyis required.

                                      TABLE 1                                     __________________________________________________________________________              Chemical Composition                                                Steel No. C  Si Mn Nb V  Mo Al Ti N                                           __________________________________________________________________________    Present                                                                              1  0.03                                                                             0.28                                                                             1.46                                                                             0.05                                                                             0.07                                                                             -- 0.029                                                                            0.021                                                                            0.0068                                      Invention                                                                            2  0.05                                                                             0.32                                                                             1.54                                                                             0.04                                                                             0.05                                                                             0.20                                                                             0.019                                                                            0.014                                                                            0.0047                                             3  "  "  "  "  "  "  "  "  "                                                  4  "  "  "  "  "  "  "  "  "                                                  5  0.05                                                                             0.22                                                                             1.82                                                                             0.06                                                                             -- 0.26                                                                             0.031                                                                            0.011                                                                            0.0052                                             6  "  "  "  "  -- "  "  "  "                                           Comparison                                                                           7  0.05                                                                             0.32                                                                             1.54                                                                             0.04                                                                             0.05                                                                             0.20                                                                             0.019                                                                            0.014                                                                            0.0047                                             8  "  "  "  "  "  "  "  "  "                                                  9  "  "  "  "  "  "  "  "  "                                                  10 0.12                                                                             0.21                                                                             1.46                                                                             0.05                                                                             0.06                                                                             -- 0.023                                                                            -- 0.0081                                             11 0.03                                                                             0.24                                                                             1.51                                                                             0.04                                                                             0.05                                                                             0.10                                                                             0.029                                                                            -- 0.0061                                             12 0.08                                                                             0.29                                                                             1.39                                                                             0.06                                                                             -- 0.18                                                                             0.021                                                                            0.042                                                                            0.0088                                      __________________________________________________________________________    Productions Conditions                                                        Ingot or Slab production Step  Thick plate Production Step                    Continuous                          Heated Reduc-                                                                             Finish-                                                                           Final                     Casting     Ingot-Making Method                                                                         TiN  Heating                                                                            γ grain                                                                        tion at                                                                            ing Thick-                       Average Cooling                                                                        Soaking                                                                             Cooling ≦0.02μ                                                                   Temp.                                                                              Size   930° C.                                                                     Temp.                                                                             ness                      No.                                                                              Rate (°C./min.)*.sup.1                                                          Temp.(°C.)                                                                   Rate (°C./min.)                                                                (%)*.sup.2                                                                         (°C.)                                                                       (ASTM No.)                                                                           or below                                                                           (°C.)                                                                      (mm)                      __________________________________________________________________________    1  20.0     --    --      0.0093                                                                             1050 7.0    80   760 20                        2  --       1350  1.0     0.0062                                                                             1150 4.5    75   730 20                        3  --       "     "       "    "    "      75   800 20                        4  --       "     "       "    "    "      55   740 20                        5  --       1320  60      0.0052                                                                             1150 5.0    65   740 25                        6  --       "     "       "    "    "      80   690 25                        7  --       1350  1.0     0.0062                                                                             1150 5.0    35   730 20                        8  --       "     "       "    "    "      55   850 20                        9  --       "     "       "    1150 0.5    75   740 20                        10 --       1350  1.0     --   1150 1.0    75   720 16                        11 --       1350  1.0     --   1150 0.5    80   760 20                        12 20.0     --    --      0.0026                                                                             1150 1.0    75   720 20                        __________________________________________________________________________                         Properties*.sup.3                                                             Yield Point                                                                         Tensile Strength                                                                       Elongation                                                                          vE-60° C.*.sup.4                                                             vTrs                                                                              pT.sub.100 *.sup.5                          No.                                                                              (kg/mm.sup.2)                                                                       (kg/mm.sup.2)                                                                          (%)   (kg-m)                                                                              (°C.)                                                                      (°C.)              __________________________________________________________________________                      1  53.0  59.8     44    24.1  -138                                                                              -80                                         2  55.6  65.7     41    22.8  -132                                                                              -74                                         3  49.1  63.6     42    24.2  -123                                                                              -66                                         4  53.2  63.1     41    25.3  -114                                                                              -58                                         5  47.8  65.9     48    25.9  -142                                                                              -78                                         6  53.9  70.3     44    21.2  -128                                                                              -69                                         7  50.3  60.9     43    21.9  -76 -34                                         8  38.8  55.3     44    23.2  -82 -32                                         9  56.2  65.8     41    20.1  -92 -46                                         10 53.2  59.9     41    16.8  -91 -26                                         11 53.8  63.3     43    20.2  -98 -48                                         12 52.8  61.9     42    17.2  -82 -32                       __________________________________________________________________________     *.sup.1 Average cooling rate at the center portion of the slab between th     molten steel temperature and 1100° C.                                  *.sup.2 Contents in the steel before the heating for the final rolling        *.sup.3 All properties are values at right angle to the final rolling         direction.                                                                    *.sup.4 Charpy test pieces were taken from the center of the plate            thickness.                                                                    *.sup.5 100% ductility transition temperature by 2mmV press notch Charpy      test.                                                                    

                                      TABLE 2                                     __________________________________________________________________________             Chemical Composition                                                 Steel No.                                                                              C  Si Mn  Nb V  Mo  Al Ti N    S  REM                                                                              Ca   REM/S                      __________________________________________________________________________    Present                                                                              1 0.05                                                                             0.32                                                                             1.54                                                                              0.04                                                                             0.05                                                                             0.20                                                                              0.019                                                                            0.014                                                                            0.0047                                                                             0.004                                                                            0.009                                                                            --   2.3                        Invention                                                                            2 0.03                                                                             0.28                                                                             1.47                                                                              0.06                                                                             -- 0.23                                                                              0.032                                                                            0.016                                                                            0.0059                                                                             0.003                                                                            0.012                                                                            0.0008                                                                             4.0                               3 "  "  "   "  -- "   "  "  "    "  "  "    "                          Comparison                                                                           4 0.09                                                                             0.31                                                                             1.48                                                                              0.04                                                                             0.05                                                                             0.12                                                                              0.023                                                                            -- 0.0032                                                                             0.003                                                                            0.0011                                                                           3.0                             __________________________________________________________________________    Production Conditions                                                         Ingot or Slab Production Step  Thick Plate Production Step                    Continuous                          Heated Reduc-                                                                             Finish-                                                                           Final                     Casting     Ingot-Making*.sup.1 TiN                                                                          Heating                                                                            γ grain                                                                        tion at                                                                            ing Thick-                       Average Cool-                                                                          Soaking                                                                             Cooling ≦0.02μ                                                                   Temp.                                                                              Size   930° C.                                                                     Temp.                                                                             ness                      No.                                                                              ing Rate (°C.min)                                                               Temp.(°C.)                                                                   Rate (°C./min.)                                                                (%)*.sup.1                                                                         (°C.)                                                                       (ASTM No.)                                                                           or below                                                                           (°C.)                                                                      (mm)                      __________________________________________________________________________    1  --       1350  1.0     0.0062                                                                             1150 4.5    75   740 25                        2  --       1350  60      0.0058                                                                             1150 5.0    75   770 20                        3  --       "     "       "    1050 6.5    70   760 20                        4  --       1320  1.0     --   1150 0.5    75   720 20                        __________________________________________________________________________                         Properties                                                                    Yield Point                                                                         Tensile Strength                                                                       Elongation                                                                          vE-60° C.                                                                    vTrs                                                                              pT.sub.100                                  No.                                                                              (kg/mm.sup.2)                                                                       (kg/mm.sup.2)                                                                          (%)   (kg-m)                                                                              (°C.)                                                                      (°C.)              __________________________________________________________________________                      1  53.6  63.7     45    26.3  -140                                                                              -87                                         2  52.5  62.6     42    28.9  -148                                                                              -81                                         3  50.3  60.9     43    29.2  -152                                                                              -103                                        4  52.1  60.6     42    20.6  -103                                                                              -59                       __________________________________________________________________________     *.sup.1 Contents in the steel before the heating for the final rolling   

                                      TABLE 3                                     __________________________________________________________________________              Chemical Composition                                                Steel No. C  Si Mn Nb V  Mo Cr Ni Cu Al Ti  N                                 __________________________________________________________________________    Present                                                                              1  0.06                                                                             0.22                                                                             0.82                                                                             0.03                                                                             -- 0.21                                                                             -- 2.30                                                                             -- 0.024                                                                            0.016                                                                             0.0073                            Invention                                                                            2  "  "  "  "  -- "  -- "  -- "  "   "                                        3  0.04                                                                             0.32                                                                             1.46                                                                             0.05                                                                             0.04                                                                             0.18                                                                             -- 1.30                                                                             0.32                                                                             0.021                                                                             0.0053                                                                    0.012                                           4  0.06                                                                             0.38                                                                             1.28                                                                             0.03                                                                             0.03                                                                             0.10                                                                             0.52                                                                             0.93                                                                             -- 0.028                                                                            0.014                                                                             0.0048                                   5  0.05                                                                             0.29                                                                             0.91                                                                             0.06                                                                             -- 0.20                                                                             -- 3.02                                                                             -- 0.033                                                                            0.021                                                                             0.0078                                   6  "  "  "  "  -- "  -- "  -- "  "   "                                 Comparison                                                                           7  0.06                                                                             0.22                                                                             0.82                                                                             0.03                                                                             -- 0.21                                                                             -- 2.30                                                                             -- 0.024                                                                            0.016                                                                          0.0073                                      8  "  "  "  "  -- "  -- "  -- "  "   "                                        9  0.03                                                                             0.31                                                                             1.39                                                                             0.06                                                                             0.05                                                                             0.15                                                                             -- 1.38                                                                             0.39                                                                             0.028                                                                            --  0.0081                                   10 "  "  "  "  "  "  -- "  "  "  --  "                                 __________________________________________________________________________    Production Conditions                                                                                         Thick Plate Production Step                   Ingot or Slab Production Step        Heated Reduc-                                                                             Finish-                                                                           Final                    Continuous Casting                                                                         Ingot-Making Method                                                                          TiN Heating                                                                            γ grain                                                                        tion at                                                                            ing Thick-                      Average Cooling                                                                         Soaking                                                                              Cooling ≦0.2μ                                                                   Temp.                                                                              Size   930° C.                                                                     Temp.                                                                             ness                     No.                                                                              Rate (°C./min.)*.sup.1                                                           Temp. (°C.)                                                                   Rate (°C./min.)                                                                (%)*.sup.2                                                                        (°C.)                                                                       (ASTM No.)                                                                           or below                                                                           (°C.)                                                                      (mm)                     __________________________________________________________________________    1  --        1350   60      0.0069                                                                            1150 5.0    80   720 35                       2  --        "      "       "   1050 7.0    55   720 35                       3  --        1350   1.0     0.0054                                                                            1050 6.5    75   740 35                       4  --        1350   1.0     0.0058                                                                            1150 4.5    65   720 25                       5  20.0      --     --      0.0082                                                                            1150 5.0    75   740 35                       6  "         --     --      "   "    "      65   810 35                       7  --        1350   60      0.0069                                                                            1150 5.0    40   720 35                       8  --        "      "       "   1050 7.0    55   830 35                       9  20.0      --     --      --  1150 1.5    75   760 35                       10 "         --     --      --  1050 2.5    75   760 35                       __________________________________________________________________________                          Properties                                                                    Yield Point                                                                         Tensile Strength                                                                       Elongation                                                                          vE-60° C.                                                                    vTrs                                                                              pT.sub.100                                  No.                                                                              (kg/mm.sup.2)                                                                       (kg/mm.sup.2)                                                                          (%)   (kg-m)                                                                              (°C.)                                                                      (°C.)             __________________________________________________________________________                       1  52.3  67.3     49    23.2  -128                                                                              -71                                         2  53.6  68.2     50    25.8  -134                                                                              -79                                         3  46.8  62.4     49    24.3  -133                                                                              -80                                         4  50.4  65.0     46    22.5  -126                                                                              -72                                         5  53.8  68.7     50    23.8  -135                                                                              -79                                         6  49.2  62.9     51    26.2  -121                                                                              - 70                                        7  51.9  68.8     50    17.4   -96                                                                              -48                                         8  39.5  54.6     51    20.1   -89                                                                              -39                                         9  47.4  63.5     47    15.2   -97                                                                              -38                                         10 48.6  64.2     48    19.2  -102                                                                              -43                      __________________________________________________________________________     *.sup.1 Average cooling rate at the center portion of the slab between th     molten steel temperature and 1100° C.                                  *.sup.2 Contents in the steel before the heating for the final rolling   

                                      TABLE 4                                     __________________________________________________________________________    Steel*                                                                             Chemical Composition (wt. %)                                             No.  C  Si Mn P  S  Al O  N   Ti Nb V  Mo Others                              __________________________________________________________________________    O  Al                                                                              0.04                                                                             0.26                                                                             1.52                                                                             0.016                                                                            0.004                                                                            0.036                                                                            0.006                                                                            0.0050                                                                            0.014                                                                            0.037                                                                            0.061                                                                            0.24                                                                             --                                     A2                                                                              "  "  "  "  "  "  "  "   "  "  "  "  --                                     A3                                                                              "  "  "  "  "  "  "  "   "  "  "  "  --                                  O  B1                                                                              0.08                                                                             0.20                                                                             1.38                                                                             0.012                                                                            0.003                                                                            0.028                                                                            0.005                                                                            0.0049                                                                            0.012                                                                            0.030                                                                            -- 0.28                                                                             Ni 1.60                                B2                                                                              "  "  "  "  "  "  "  "   "  "  -- "  "                                      B3                                                                              "  "  "  "  "  "  "  "   "  "  -- "  "                                   0  C1                                                                              0.03                                                                             0.25                                                                             1.90                                                                             0.008                                                                            0.004                                                                            0.035                                                                            0.004                                                                            0.0051                                                                            0.007                                                                            0.041                                                                            -- 0.31                                                                             Rare earth                                                                    element 0.02                           C2                                                                              "  "  "  "  "  "  "  "   "  "  -- "  Rare earth                                                                    element 0.02                           C3                                                                              "  "  "  "  "  "  "  "   "  "  -- "  Rare earth                                                                    element 0.02                           I 0.13                                                                             0.18                                                                             1.26                                                                             0.020                                                                            0.003                                                                            0.050                                                                            0.006                                                                            0.0051                                                                            0.015                                                                            0.036                                                                            0.071                                                                            0.30                                                                             Ni 0.60                                J 0.08                                                                             0.19                                                                             1.52                                                                             0.013                                                                            0.006                                                                            0.041                                                                            0.006                                                                            0.0075                                                                            -- 0.051                                                                            0.060                                                                            -- Rare earth                                                                    element 0.02                           K 0.06                                                                             0.26                                                                             1.45                                                                             0.019                                                                            0.005                                                                            0.036                                                                            0.005                                                                            0.0061                                                                            0.046                                                                            -- -- -- --                                     L 0.08                                                                             0.25                                                                             1.36                                                                             0.025                                                                            0.014                                                                            0.030                                                                            0.006                                                                            0.0050                                                                            0.010                                                                            0.041                                                                            -- 0.30                                                                             --                                  O  M 0.02                                                                             0.11                                                                             1.65                                                                             0.020                                                                            0.003                                                                            0.026                                                                            0.005                                                                            0.0055                                                                            0.013                                                                            0.011                                                                            0.056                                                                            0.27                                                                             Ni 0.20;                                                                      Cu 0.26;                                                                      Rare earth                                                                    element 0.009                       O  N 0.08                                                                             0.15                                                                             1.38                                                                             0.018                                                                            0.003                                                                            0.030                                                                            0.006                                                                            0.0070                                                                            0.012                                                                            0.060                                                                            0.080                                                                            -- Ni 0.76;                                                                      Ca 0.008                            __________________________________________________________________________                           Ingot or Slab Production Step                                                 Continuous                                                                             Ingot-Making                                                         Casting  Method Cooling                                                                             Tin                                                     Average Cooling                                                                        Soaking                                                                              Rate  ≦0.02μ                                        Rate (°C./min.)*.sup.1                                                          Temp. (°C.)                                                                   (°C./min.)                                                                   (%)*.sup.2                       __________________________________________________________________________                           --       1350   1.0   0.0068                                                  --       "      "     0.0060                                                  --       "      "     0.0062                                                  --       1320   1.0   0.0059                                                  --       "      "     0.0057                                                  --       "      "     0.0056                                                  --       1350   60    0.0060                                                  --       "      "     0.0059                                                  --       "      "     0.0061                                                  --       1320   1.0   0.0048                                                  --       1350   60    --                                                      --       1350   1.0   0.0030                                                  19.0     --     --    0.0076                                                  18.5     --     --    0.0088                                                  --       1350   60    0.0069                           __________________________________________________________________________              Hot Rolling Conditions                                                        Slab   Heated Total  Finishing                                                                            Reheating Step                                    Heating                                                                              γ Grain                                                                        Reduction                                                                            Rolling                                                                              Holding                                                                              Holding                                    Temperature                                                                          Size   at 900° C.                                                                    Temperature                                                                          Temperature                                                                          Time                                       (°C.)                                                                         (ASTM No.)                                                                           or below (%)                                                                         (°C.)                                                                         (°C.)                                                                         (min.)                           __________________________________________________________________________              1150   6.5    70     720    630    30                                         "      6.0    "      "      --     --                                         "      6.5    45     800    630    30                                         1150   6.0    70     720    600    20                                         "      5.5    "      "      --     --                                         "      5.5    55     770    600    20                                         1150   6.5    70     700    660    40                                         1250   6.5    55     750    "      "                                          "      6.5    60     820    "      "                                          1150   4.0    70     720    630    30                                         1150   0.5    70     730    640    30                                         1250   1.5    70     700    650    20                                         1150   6.5    65     690    630    30                                         1050   7.0    70     720    530     5                                         1150   6.5    65     700    590    20                               __________________________________________________________________________                                          Charpy                                                                              Hydrogen                                            Toughness Properties                                                                              Impact                                                                              Induced                                             2mmV Charpy         Absorbed                                                                            Cracking                                            Impact Test         Energy at                                                                           Resistance                                          Absorbed            Welded                                                                              Number of                         Tensile Properties                                                                              Impact        B. DWTT                                                                             Portion                                                                             Cross                             Product                                                                             Yield Tensile                                                                             Energy at                                                                            Transition                                                                           85%   -40° C.                                                                      Sectional                         Thickness                                                                           Point Strength                                                                            VE -40° C.                                                                    Temperature                                                                          SATT  2mmV  Crackings                         (mm)  (kg/mm.sup.2)                                                                       (Kg/mm.sup.2)                                                                       (kg-m) vTrs (°C.)                                                                    (°C.)                                                                        (Kg-m)                                                                              (mm)                              __________________________________________________________________________    32    54    64    27     -120   -55   18    0                                 "     50    62    16     -80    -35   16    4                                 "     48    61    14     -85    -30   17    1                                 26    57    68    30     -140   -80   16    1                                 "     54    63    17     -90    -50   15    8                                 "     55    66    19     -100   -40   16    5                                 41    65    75    13     -110   -45   8     1                                 "     59    72    7      -95    -20   5     7                                 "     58    71    4      -90    -15   7     6                                 26    50    63    8      -45    -25   12    7                                 26    52    64    4      -40    -15   6     3                                 32    51    63    7      -60    -30   7     5                                 26    50    62    6      -40    -15   2     9                                 32    53    64    25     -120   -55   24    0                                 26    56    66    18     -105   -50   12    1                                 __________________________________________________________________________     *Steels manufactured by the present invention are marked with a circle        (O).                                                                          *.sup.1 Average cooling rate at the center portion of the slab between th     molten steel temperature and 1100° C.                                  *.sup.2 Contents in the steel before the heating for the final rolling   

What is claimed is: .[.
 1. A process for producing a high tension steelsheet having excellent low-temperature toughness with a yield point notlower than 40 kg/mm² which comprises heating a steel ingot or slab to atemperature not higher than 1150° C., and rolling the steel ingot orslab thus heated with a total reduction amount not less than 50% in atemperature range not higher than 930° C. and a finishing temperaturenot higher than 830° C.,said steel ingot or slab containing 0.01 to0.13% C, 0.1 to 1.0% Si, 0.7 to 2.0% Mn, not more than 0.1% total Al,0.004 to 0.03% Ti, 0.001 to 0.009% total N, 0.01 to 0.10% Nb, 0.01 to0.15% V, 0.05 to 0.40% Mo, with the balance being unavoidable impuritiesand Fe, in which (Nb%)×(C%)≦5×10⁻³ and TiN not larger than 0.02μ is notless than 0.004%..]. .[.2. A process for producing a high tension steelsheet having excellent low-temperature toughness with a yield point notlower than 40 kg/mm² which comprises heating a steel ingot or slab to atemperature not higher than 1150° C., and rolling the steel ingot orslab thus heated with a total reduction amount not less than 50% in atemperature range not higher than 930° C. and a finishing temperaturenot higher than 830° C., said steel ingot or slab containing 0.01 to0.13% C, 0.1 to 1.0% Si, 0.7 to 2.0% Mn, not higher than 0.1% total Al,0.004 to 0.03% Ti, 0.001 to 0.009% total N, 0.01 to 0.10% Nb, 0.05 to0.40% Mo, 0.01 to 0.15% V, and one or both of 0.001 to 0.03% REM, 0.0005to 0.03% Ca, with the balance being unavoidable impurities and Fe inwhich (Nb%)×(C%)≦5×10⁻³, REM/S=1.0 to 6.0 in case of REM addition, andTiN not larger than 0.02μ is not less than 0.004%..]. .[.3. A processfor production a high tension steel sheet having excellentlow-temperature toughness with a yield point not lower than 40 kg/mm²which comprises heating a steel ingot or slab to a temperature nothigher than 1150° C. and rolling the steel ingot or slab thus heatedwith a total reduction amount not less than 50% in a temperature rangenot higher than 930° C. and a finishing temperature not higher than 830°C., said steel ingot or slab containing 0.01 to 0.13% C, 0.1 to 1.0% Si,0.7 to 2.0% Mn, not more than 0.1% total Al, 0.004 to 0.03% Ti, 0.001 to0.009% total N, 0.01 to 0.10% Nb, 0.01 to 0.15% V and 0.05 to 0.40% Mo,one or more of not more than 0.6% Cr, not more than 1.0% Cu, and notmore than 4.0% Ni with the balance being unavoidable impurities and Fein which

    (Nb%)×(C%)≦5×10.sup.-3

    (Cu+Ni)/5+Cr+Mo≦0.90%

and TiN not larger than 0.02μ is not less than 0.004%..]. .[.4. Aprocess for producing a high tension steel sheet having excellentlow-temperature toughness with a yield point not lower than 40 kg/mm²which comprises heating a steel ingot or slab to a temperature nothigher than 1150° C. and rolling the steel ingot or slab thus heatedwith a total reduction amount not less than 50% in a temperature rangenot higher than 930° C. and a finishing temperature not higher than 830°C.,said steel ingot or slab containing 0.01 to 0.13% C, 0.1 to 1.0% Si,0.7 to 2.0% Mn, not more than 0.1% total Al, 0.004 to 0.03% Ti, 0.001 to0.009% total N, 0.01 to 0.10% Nb, 0.01 to 0.15% V, 0.05 to 0.40% Mo, oneor both of 0.001 to 0.03% REM and 0.0005 to 0.03% Ca, and one or more ofnot more than 0.6% Cr, not more than 1.0% Cu and not more than 4.0% Niwith the balance being unavoidable impurities and Fe, in which

    (Nb%)×(C%)≦5×10.sup.-3

    REM/S=1.0 to 6.0 in case of REM addition

    (Cu×Ni)/5+Cr+Mo≦0.90%

and TiN not larger than 0.02μ is not less than 0.004%..]. .Iadd.
 5. Aprocess for producing steel sheet suitable for pipe lines, havingexcellent low temperature toughness with a yield point of 40 kg/mm² orhigher and a vTrs value of about -110° C. lower for a 50% reduction ofthe steel comprising continuously casting a molten steel into the formof a slab, said molten steel containing 0.01 to 0.13% C, 0.1 to 1.0% Si,0.7 to 2.0% Mn, not more than 0.1% total Al, 0.004 to 0.03% Ti, 0.001 to0.009% total N, 0.01 to 0.10% Nb, 0.05 to 127 0.40% Mo, with the balancebeing Fe and unavoidable impurities and satisfying the condition of(Nb%)×(C%)≦5×10⁻³, cooling the slab thus-obtained by continuous castingwith an average cooling rate of 8° C./min. or more as measured in thecentral portion of the slab through the temperature range from thetemperature at the time of pouring to 1100° C. to obtain a slabcontaining 0.004% or more TiN of a grain size not larger than 0.02μ,heating the slab at 1150° C. or lower and rolling the slab with a totalreduction not less than 50% at temperatures not higher than 930° C. andwith a finishing temperature not higher than 830° C. .Iaddend. .Iadd. 6.A process according to claim 5 in which the molten steel furthercontains one or more of a material selected from the group consisting of0.01 to 0.15% V, up to 0.6% Cr, up to 1.0% Cu and up to 4.0% Ni within arange of (Cu+Ni)/5+Cr+Mo≦0.90%. .Iaddend. .Iadd.
 7. A process accordingto claim 5 in which the molten steel further contains one or more of amaterial selected from the group consisting of 0.001 to 0.03% REM, and0.0005 to 0.03% Ca, and wherein REM/S is from 1.0 to 6.0. .Iaddend.